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In
recent years there has been increasingly serious concern about
the thinning of the earth's protective ozone layer. It is
a well-publicised fact that Chlorofluorocarbons (CFCs) and,
to a certain extent, hydrochlorofluorocarbons (HCFCs) are
responsible for a great deal of that damage.
Even if production and use of CFC fluids were to cease today,
their effect on the ozone layer would continue for hundreds
of years, due to their long residence time in the atmosphere.
In 1987, at Montreal, a protocol was signed by over 70 countries,
committed to phasing out the use of CFCs by the end of this
century.
This treaty had far reaching implications for industry, with
refrigeration and air-conditioning manufacturers amongst the
worst affected, as CFC refrigerants account for one-third
of all CFC consumption.
The major chemical companies who produce CFC fluids responded
quickly to identify a new, ozone friendly alternative - a
Hydrofluorocarbon known as HFC R134a. HFC R134a has zero effect
on the ozone layer and is readily degradable. Compared to
CFCs, it has one-tenth the atmospheric lifetime, and one-tenth
the effect on global warming of CFC 12.
Nevertheless, it has caused a major headache for refrigeration
system manufacturers because the mineral oil lubricants, traditionally
used in
refrigeration compressors, are immiscible with the new HFC R134a, a problem that has since been solved by Castrol, the
world leading lubricants company.
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